There is no electrical energy being created. It is just a simple acid-base reaction that a grade 8 learns about in Science class.
Calcium Hydroxicde + citric acid <---> Calcium Citrate + H-OH
Calcium Citrate is itself very insoluble but not as insoluble as calciume hydroxide, so you get a spike in TDS. No great mystery
If you are really interested these 2 sites should give you an idea of what is really going on