Taurine (500mg-3g a day). It should help improve his tinnitus by some degree and get him relaxed so a double benefit here. One down side with taurine or a plus for some is the stimulation of gastric acid production so watch the dose and start with little.
Coffee is a complex one here it might prevent it but may aggravate it once you have it.
Others worth a try: Zinc. Omega 3. B12. Calcium.
Just research them and see. Hope your dad will improve.