Two things that come to mind are internal bentonite/psyllium cleanses. If you are clean internally it will reflect to some degree externally. Bentonite clay ACV masks will help topically. I have also heard good reports about the healing power of Castor oil. Been using it myself and notice better complexion, less dark spots, wrinkles etc. more here http://www.electroherbalism.com/Naturopathy/Therapies/Diet/FatsandOils/Castor...
Peace
Steve
PS as for the emotional side of it I can definitely help you with that. PM me.