There are several forms of mercury, of which Methylmercury is the most toxic form. It affects the immune system, alters genetic and enzyme systems, and damages the nervous system, including coordination and the senses of touch, taste, and sight. Methylmercury is particularly damaging to developing embryos, which are five to ten times more sensitive than adults. Exposure to methylmercury is usually by ingestion, and it is absorbed more readily and excreted more slowly than other forms of mercury. Elemental mercury on the other hand, is absorbed relatively slowly and may pass through the digestive system without causing damage. Ingestion of other common forms of mercury, such as the salt HgCl2, which damages the gastrointestinal tract and causes kidney failure, is unlikely from environmental sources. Naturally grown plant foods don't contain methymercury.
People are exposed to methylmercury almost entirely by eating contaminated fish and wildlife that are at the top of aquatic foodchains. The National Research Council, in its 2000 report on the toxicological effects of methylmercury, pointed out that the population at highest risk is the offspring of women who consume large amounts of fish and seafood. The report went on to estimate that more than 60,000 children are born each year at risk for adverse neurodevelopmental effects due to in utero exposure to methylmercury. In its 1997 Mercury Study Report to Congress, the U.S. Environmental Protection Agency concluded that mercury also may pose a risk to some adults and wildlife populations that consume large amounts of fish that is contaminated by mercury.
Fish-eating birds in certain parts of the United States may also ingest large amounts of methylmercury in their diet.
Sources of Mercury
Alkali and metal processing, incineration of coal, and medical and other waste, and mining of gold and mercury contribute greatly to mercury concentrations in some areas, but atmospheric deposition is the dominant source of mercury over most of the landscape. Once in the atmosphere, mercury is widely disseminated and can circulate for years, accounting for its wide-spread distribution. Natural sources of atmospheric mercury include volcanoes, geologic deposits of mercury, and volatilization from the ocean. Although all rocks, sediments, water, and soils naturally contain small but varying amounts of mercury, scientists have found some local mineral occurrences and thermal springs that are naturally high in mercury.
Methylation is a product of complex processes that move and transform mercury. Atmospheric deposition contains the three principal forms of mercury, although inorganic divalent mercury (HgII) is the dominant form. Once in surface water, mercury enters a complex cycle in which one form can be converted to another. Mercury attached to particles can settle onto the sediments where it can diffuse into the water column, be resuspended, be buried by other sediments, or be methylated. Methylmercury can enter the food chain, or it can be released back to the atmosphere by volatilization.
The concentration of dissolved organic carbon (DOC) and pH have a strong effect on the ultimate fate of mercury in an ecosystem. Studies have shown that for the same species of fish taken from the same region, increasing the acidity of the water (decreasing pH) and/or the DOC content generally results in higher mercury levels in fish, an indicator of greater net methylation. Higher acidity and DOC levels enhance the mobility of mercury in the environment, thus making it more likely to enter the food chain.
Mercury and methylmercury exposure to sunlight (specifically ultra-violet light) has an overall detoxifying effect. Sunlight can break down methylmercury to Hg(II) or Hg(0), which can leave the aquatic environment and reenter the atmosphere as a gas.
Sampling mercury in water requires extra care to avoid cross contamination because concentrations in water are so low.
Although mercury is a globally dispersed contaminant, it is not a problem everywhere. Aside from grossly polluted environments, mercury is normally a problem only where the rate of natural formation of methylmercury from inorganic mercury is greater than the reverse reaction. Methylmercury is the only form of mercury that accumulates appreciably in fish.
Plants exposed to natural UV-light during the growth process release any methylmercury. Birds and fish are unable to do that.
Thank you for your vigilent comments and helping to bring more clarity into this subject.
Andreas
Reference:
http://www.usgs.gov/themes/factsheet/146-00/